No renderable structure data available
CC(C)(C)OC(=O)CCCCCCCCCCCCCCBrChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | tert-butyl 15-bromopentadecanoate |
|---|---|
| IUPAC Name | — |
| CAS Number | 905302-64-9 |
| Database ID | 58079429 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
tert-butyl 15-bromopentadecanoate (CAS 905302-64-9) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 58079429
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
11 reactions · 11 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-51c43d0c90e3490593a2f4460f28c1bbConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-069f7f938d00444aae531b478972dc9dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-73f4cdf9bcdd48268188b0ef2f94e35cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-73f4cdf9bcdd48268188b0ef2f94e35cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-2ac38b540b7847bfab8389a7a3bb1c02Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-5f9ad986631c45cdbf6d5fea2d3431d0Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-51c43d0c90e3490593a2f4460f28c1bbConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-069f7f938d00444aae531b478972dc9dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-73f4cdf9bcdd48268188b0ef2f94e35cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Hydroxy-isophthalic acid dimethyl ester (420 mg, 2 mmol), 15-bromo-pentadecanoic acid tert-butyl ester (755 mg, 2 mmol) and K2CO3 (415 mg, 3 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed by TLC (4:1 heptane/AcOEt), which indicated reaction completion after 6 h. The sample was concentrated to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield a white crystalline solid (1.0 g, 100%). refluxed under N2 reaction completion after 6 h The sample was concentrated AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-2ac38b540b7847bfab8389a7a3bb1c02Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 15-Bromo-pentadecanoic acid tert-butyl ester (598 mg, 1.59 mmol), 4-hydroxy isophthalic acid 3-tert-butyl ester 1-methyl ester (400 mg, 1.59 mmol) and K2CO3 (329 mg, 2.38 mmol) were placed in a flask with acetonitrile (25 ml) and refluxed under N2. The reaction was followed via TLC (4:1 heptane/AcOEt). After 13 h the sample was concentrated under vacuum to near dryness. AcOEt (50 ml) and water (25 ml) were added to the residue. The phases were separated and the organic phase was washed with water and brine (25 ml each), dried over MgSO4 and concentrated to yield an oil (841 mg, 97%). refluxed under N2 After 13 h the sample was concentrated under vacuum AcOEt (50 ml) and water (25 ml) were added to the residue The phases were separated the organic phase was washed with water and brine (25 ml each) dried over MgSO4 concentrated
Source ID: ord-5f9ad986631c45cdbf6d5fea2d3431d0PubChem References
These sources are listed in the compound's public database record.
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