No renderable structure data available
CCOC(=O)C(Cl)(Cl)ClChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | ethyl 2,2,2-trichloroacetate |
|---|---|
| IUPAC Name | — |
| CAS Number | 515-84-4 |
| Database ID | 10588 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
ethyl 2,2,2-trichloroacetate (CAS 515-84-4) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 10588
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-f7c04016b5e0452388080ca7d82cfe26Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-71d708329f3446f59d5ae6e5af9cdbacConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-5f282c9ef17241e19e49848e7bfe609aConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 0.60 g of 4-(2,6-dichloro-4-(3,3-dichloro-2-propenyloxy)phenoxy)butyloxyacetaldehyde, 0.29 g of zinc dust and 10 ml of N,N-dimethylformamide was added ethyl trichloroacetate with stirring at room temperature. After stirring at room temperature for 2 hours, the reaction mixture was poured into 10 ml of diluted hydrochloric acid and extracted twice with diethyl ether. The diethyl ether layers were combined, washed with water, dried over magnesium sulfate and then evaporated to give a crude product. The crude product was subjected to silica gel chromatography, which afforded 0.04 g of 3,5-dichloro-1-(3,3-dichloro-2-propenyloxy)-4-(4-(3-chloro-3-ethoxycarbonyl-2-propenyloxy)butyloxy)benzene (yield, 5%), nD23.0 1.5348. After stirring at room temperature for 2 hours extracted twice with diethyl ether washed with water dried over magnesium sulfate evaporated to give a crude product
Source ID: ord-5d15c627687f44229f5bee816b68686dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Ethanol is reacted with trichloroacetic anhydride to yield ethyltrichloroacetate.
Source ID: ord-1d4b404771e248cdb8fa59d34b337750Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Ethanol is reacted with trichloroacetic anhydride to yield ethyltrichloroacetate.
Source ID: ord-1d4b404771e248cdb8fa59d34b337750Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: In a 10 mL round-bottom flask, 1.88 g of diethyl ethylmalonate (10 mmol), 2.10 g of ethyl trichloroacetate (11 mmol), 158 mg of tetra-n-butylammonium fluoride trihydrate (0.5 mmol), and 69 mg of potassium carbonate (0.5 mmol) were stirred at 24° C. for 5 h. After filtration, the solution was found to contain 1.56 g (70% yield) of diethyl α-chloro-α-ethylmalonate. After filtration
Source ID: ord-bf9b038c957d4ccf9eda320c0a3fec1aConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 0.60 g of 4-(2,6-dichloro-4-(3,3-dichloro-2-propenyloxy)phenoxy)butyloxyacetaldehyde, 0.29 g of zinc dust and 10 ml of N,N-dimethylformamide was added ethyl trichloroacetate with stirring at room temperature. After stirring at room temperature for 2 hours, the reaction mixture was poured into 10 ml of diluted hydrochloric acid and extracted twice with diethyl ether. The diethyl ether layers were combined, washed with water, dried over magnesium sulfate and then evaporated to give a crude product. The crude product was subjected to silica gel chromatography, which afforded 0.04 g of 3,5-dichloro-1-(3,3-dichloro-2-propenyloxy)-4-(4-(3-chloro-3-ethoxycarbonyl-2-propenyloxy)butyloxy)benzene (yield, 5%), nD23.0 1.5348. After stirring at room temperature for 2 hours extracted twice with diethyl ether washed with water dried over magnesium sulfate evaporated to give a crude product
Source ID: ord-5d15c627687f44229f5bee816b68686dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 0.60 g of 4-(2,6-dichloro-4-(3,3-dichloro-2-propenyloxy)phenoxy)butyloxyacetaldehyde, 0.29 g of zinc dust and 10 ml of N,N-dimethylformamide was added ethyl trichloroacetate with stirring at room temperature. After stirring at room temperature for 2 hours, the reaction mixture was poured into 10 ml of diluted hydrochloric acid and extracted twice with diethyl ether. The diethyl ether layers were combined, washed with water, dried over magnesium sulfate and then evaporated to give a crude product. The crude product was subjected to silica gel chromatography, which afforded 0.04 g of 3,5-dichloro-1-(3,3-dichloro-2-propenyloxy)-4-(4-(3-chloro-3-ethoxycarbonyl-2-propenyloxy)butyloxy)benzene (yield, 5%), nD23.0 1.5348. After stirring at room temperature for 2 hours extracted twice with diethyl ether washed with water dried over magnesium sulfate evaporated to give a crude product
Source ID: ord-5d15c627687f44229f5bee816b68686dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Ethanol is reacted with trichloroacetic anhydride to yield ethyltrichloroacetate.
Source ID: ord-1d4b404771e248cdb8fa59d34b337750Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-f7c04016b5e0452388080ca7d82cfe26Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-71d708329f3446f59d5ae6e5af9cdbacPubChem References
These sources are listed in the compound's public database record.
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