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CC(CCI)C(F)(F)FChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | 1,1,1-trifluoro-4-iodo-2-methylbutane |
|---|---|
| IUPAC Name | — |
| CAS Number | 339-61-7 |
| Database ID | 19090856 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
1,1,1-trifluoro-4-iodo-2-methylbutane (CAS 339-61-7) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 19090856
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
10 reactions · 10 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-aafb6c23450d4eddba34d240812a42faConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-aafb6c23450d4eddba34d240812a42faConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washed with 10% sodium thiosulphate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether The etheric extracts are washed with 10% sodium thiosulphate and brine acid dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure
Source ID: ord-24a6d7a6ca3348caa05e4c72855707c4Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washedwith 10% sodium thiosulfate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column atatmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column atatmospheric pressure
Source ID: ord-4b3f1f6ae26c43f688ce3995e2a7fce3Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washedwith 10% sodium thiosulfate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column atatmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column atatmospheric pressure
Source ID: ord-4b3f1f6ae26c43f688ce3995e2a7fce3Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washed with 10% sodium thiosulfate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether The etheric extracts are washed with 10% sodium thiosulfate and brine acid dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure
Source ID: ord-a9154cd09dd14cfd8ccd44b549ccabe9Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washed with 10% sodium thiosulfate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether The etheric extracts are washed with 10% sodium thiosulfate and brine acid dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure
Source ID: ord-1c6d2eab94384add8958c224ddad4439Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washed with 10% sodium thiosulphate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether The etheric extracts are washed with 10% sodium thiosulphate and brine acid dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure
Source ID: ord-24a6d7a6ca3348caa05e4c72855707c4Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g potassium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washedwith 10% sodium thiosulfate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column atatmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76°-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column atatmospheric pressure
Source ID: ord-4b3f1f6ae26c43f688ce3995e2a7fce3Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To a mixture of 19 g phosphoric acid (98%) and 19 g pottasium iodide are added at 40° under stirring 4.75 g (33.4 mMol) of 4,4,4-trifluoro-3-methyl-butan-1-ol over a period of 10 minutes. The mixture is then heated at 120° for 16 hours, a cooling poured into ice-water and extracted with diethylether. The etheric extracts are washed with 10% sodium thiosulfate and brine acid dried over sodium sulphate. After filtration, the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure, followed by fractionation giving 4,4,4-trifluoro-3-methyl-1-iodo-butane, b.p. 76-77° at 140 mbar. are added at 40° The mixture is then heated at 120° for 16 hours extracted with diethylether The etheric extracts are washed with 10% sodium thiosulfate and brine acid dried over sodium sulphate After filtration the solvent is removed through a 15 cm Vigreux-column at atmospheric pressure
Source ID: ord-99adbbd40292421f97cb457941632286PubChem References
These sources are listed in the compound's public database record.
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