No renderable structure data available
CCCCCCCCOCC1CO1Chemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | 2-(octoxymethyl)oxirane |
|---|---|
| IUPAC Name | — |
| CAS Number | 3385-66-8 |
| Database ID | 92955 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
2-(octoxymethyl)oxirane (CAS 3385-66-8) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 92955
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-17c6f30321464456b7a9be5a1f5b129dConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-4ecd5054674f4e23a17fdb8008e7c790Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-950fcfcfd3494a16baf98414f974e527Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-7cc9957c04324dab9451ca8bf3da89deConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-5ba3983bd73a49dd8f49a30d93c230afConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 50 mL of Catalyst B, 40.0 g of stearyl glycidyl ether (SGE) and 22.8 g of octyl glycidyl ether (OGE) were added to 210 ml of toluene, and a vessel was closed. The polymerization was carried out at 130° C. for 24 hours with stirring. The reaction solution was added to a large amount of acetone containing a small amount of a dilute solution of hydrogen chloride. A precipitated solid was dried under reduced pressure at 80° C. for 24 hours to obtain a poly(stearyl glycidyl ether/octyl glycidyl ether) copolymer. Pale yellow solid. Yield 75%. was closed A precipitated solid was dried under reduced pressure at 80° C. for 24 hours
Source ID: ord-9909a9a5f8c54061893a864b5514024bConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Using the method of Example 5, supra, 1-octyl glycidyl ether (187 mg, 1.0 mmol) and 1,1-dimethyl-2-(4-methoxyphenyl)ethylamine (197 mg, 1.1 mmol) were used to prepare 105 mg of the title compound as a clear, colorless oil: GC/EI-MS, m/z (rel. int.) 366 (M+1, 0.08), 350 (0.08), 244 (100), 222 (5.8), 163 (12), 121 (18): 1H-NMR (CDCl3) δ 7.08 (2H, d, J=8.6), 6.82 (2H, d, J=8.6), 3.79 (1H, m), 3.77 (3H, s), 3.45 (4H, m), 2.92 (1H, broad s), 2.79 (1H, dd, J=11.6 and 4.1), 2.65 (2H, m), 2.55 (2H, m), 1.27 (8H, m), 1.06 (3H, s), 1.04 (3H, s), 0.88 (3H, t, J=6.7); 13C-NMR (CDCl3) δ 158.0, 131.2, 129.9, 113.2, 73.4, 71.6, 68.9, 55.0, 53.3, 46.2, 44.6, 31.7, 29.5, 29.3, 29.1, 26.5, 26.4, 26.0, 22.5, 14.0; FT-IR (film) cm-1 3409 (broad), 1611, 1512, 1245, 1120.
Source ID: ord-0cbbcefa26fb473dabca4c544ed2d807Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-17c6f30321464456b7a9be5a1f5b129dConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-17c6f30321464456b7a9be5a1f5b129dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 50 mL of Catalyst B, 40.0 g of stearyl glycidyl ether (SGE) and 22.8 g of octyl glycidyl ether (OGE) were added to 210 ml of toluene, and a vessel was closed. The polymerization was carried out at 130° C. for 24 hours with stirring. The reaction solution was added to a large amount of acetone containing a small amount of a dilute solution of hydrogen chloride. A precipitated solid was dried under reduced pressure at 80° C. for 24 hours to obtain a poly(stearyl glycidyl ether/octyl glycidyl ether) copolymer. Pale yellow solid. Yield 75%. was closed A precipitated solid was dried under reduced pressure at 80° C. for 24 hours
Source ID: ord-8fa80c47849a4db7b4727c00900e2b22Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Using the method of Example 5, supra, 1-octyl glycidyl ether (187 mg, 1.0 mmol) and 1,1-dimethyl-2-(4-methoxyphenyl)ethylamine (197 mg, 1.1 mmol) were used to prepare 105 mg of the title compound as a clear, colorless oil: GC/EI-MS, m/z (rel. int.) 366 (M+1, 0.08), 350 (0.08), 244 (100), 222 (5.8), 163 (12), 121 (18): 1H-NMR (CDCl3) δ 7.08 (2H, d, J=8.6), 6.82 (2H, d, J=8.6), 3.79 (1H, m), 3.77 (3H, s), 3.45 (4H, m), 2.92 (1H, broad s), 2.79 (1H, dd, J=11.6 and 4.1), 2.65 (2H, m), 2.55 (2H, m), 1.27 (8H, m), 1.06 (3H, s), 1.04 (3H, s), 0.88 (3H, t, J=6.7); 13C-NMR (CDCl3) δ 158.0, 131.2, 129.9, 113.2, 73.4, 71.6, 68.9, 55.0, 53.3, 46.2, 44.6, 31.7, 29.5, 29.3, 29.1, 26.5, 26.4, 26.0, 22.5, 14.0; FT-IR (film) cm−1 3409 (broad), 1611, 1512, 1245, 1120.
Source ID: ord-45e5443131234c6f850a48d277c1e526Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Octanol (195 g, 1.5 mole), 1.02 g (0.005 mole) of aluminum triisopropoxide and 0.7 g (0.007 mole) of 98% sulfuric acid were heated to 90° C. while stirring under a nitrogen gas atmosphere. To the reaction mixture, 92.5 g (1.0 mole) of epichlorohydrin was then added dropwise over 1 hour, followed by stirring for 4 hours. It was found that the conversion ratio of the raw material epichlorohydrin was 100%, while the yield of the resulting halohydrin ether was 95%. To the reaction mixture, 300 mL of a 4N aqueous solution of sodium hydroxide was added and the resulting mixture was stirred at 60° C. for 6 hours. After cooling to room temperature, the water layer was removed and the residue was purified by distillation under reduced pressure, whereby 175 g of octyl glycidyl ether (1,2-epoxy-4-oxadodecane) was obtained (total yield: 95%.). by stirring for 4 hours the resulting mixture was stirred at 60° C. for 6 hours the water layer was removed the residue was purified by distillation under reduced pressure
Source ID: ord-ffe5d81414c8468f955fdb706a07f59fPubChem References
These sources are listed in the compound's public database record.
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