deca-1,9-diene

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: An autoclave reactor having a volume content of 50 liters which was sufficiently substituted with nitrogen was charged in order with 20 liters of n-hexane, 12.5 mmol of triethylaluminum and 82 mmol of 1,9-decadiene and stirred for 5 minutes. Then, 3.3 g of the pre-activated metallocene supported catalyst prepared above was added, and a temperature of the reactor was elevated to 60° C. Propylene was fed so that a pressure of the reactor became a fixed pressure of 1 MPaG and reacted for 2 hours. After finishing the reaction time, 500 ml of methanol was added to terminate the reaction, and unreacted propylene was removed, followed by filtering the hexane slurry, whereby a powder of a propylene/1,9-decadiene copolymer was obtained. The powder thus obtained was dried at 60° C. for 8 hours to obtain 7 kg of the propylene/1,9-decadiene copolymer. Results of analysis thereof showed that a content of 1,9-decadiene in the copolymer was 0.03% by weight. The resulting propylene/1,9-decadiene copolymer had an MFR of 2.8 g/10 minutes. The same copolymer was produced three times to obtain total 21 kg of the propylene/1,9-decadiene copolymer, and a blend thereof was used to produce the following foamed matters. An autoclave reactor having above was added was elevated to 60° C reacted for 2 hours was added to terminate the reaction, and unreacted propylene was removed by filtering the hexane slurry, whereby a powder of a propylene/1,9-decadiene copolymer was obtained The powder thus obtained was dried at 60° C. for 8 hours

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: A mixture of cyclooctene and ethylene was contacted with catalyst and adjuvant as in Examples IX and X at room temperature and 25 psi pressure to yield 13 weight percent 1,9-decadiene. This shows that ethylene and a cyclic olefin are converted to an acyclic polyene. was contacted with catalyst and adjuvant as in Examples IX and X at room temperature

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: This Example shows use alternative dienes to 1,7-octadiene. 1,9-decadiene (55.2 g, 0.40 mol) and maleic anhydride (19.6 g, 0.20 mol) in acetone (200 g) was polymerized in the same apparatus and under the same conditions as Example 4. The yield of desired copolymer was 33.2 g. The 1H NMR showed 17 mole % vinyl octyl protons, 15 mole % saturated octyl protons, and 4.3 mole % phenyl protons from the benzoyl peroxide initiator. Further characterization is presented in Table 2 and in FIG. 2, as discussed below.

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: This Example shows use alternative dienes to 1,7-octadiene. 1,9-decadiene (55.2 g, 0.40 mol) and maleic anhydride (19.6 g, 0.20 mol) in acetone (200 g) was polymerized in the same apparatus and under the same conditions as Example 4. The yield of desired copolymer was 33.2 g. The 1H NMR showed 17 mole % vinyl octyl protons, 15 mole % saturated octyl protons, and 4.3 mole % phenyl protons from the benzoyl peroxide initiator. Further characterization is presented in Table 2 and in FIG. 2, as discussed below.

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: This Example shows use alternative dienes to 1,7-octadiene. 1,9-decadiene (55.2 g, 0.40 mol) and maleic anhydride (19.6 g, 0.20 mol) in acetone (200 g) was polymerized in the same apparatus and under the same conditions as Example 4. The yield of desired copolymer was 33.2 g. The 1H NMR showed 17 mole % vinyl octyl protons, 15 mole % saturated octyl protons, and 4.3 mole % phenyl protons from the benzoyl peroxide initiator. Further characterization is presented in Table 2 and in FIG. 2, as discussed below.

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 1,8-decadiene; 1,9-decadiene;

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: The organic phase was first rapidly distilled in order to remove the catalyst from it, then was rectified, with 47.0 g (0.276 mol) of 1,2,9,10-diepoxydecane, with a yield of 54%; 1.96 g of unreacted 1,9-decadiene (3%); and 23.0 g of 1,2-epoxy-9-decene (29%) being obtained. The organic phase was first rapidly distilled in order to remove the catalyst from it

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: This Example shows use alternative dienes to 1,7-octadiene. 1,9-decadiene (55.2 g, 0.40 mol) and maleic anhydride (19.6 g, 0.20 mol) in acetone (200 g) was polymerized in the same apparatus and under the same conditions as Example 4. The yield of desired copolymer was 33.2 g. The 1H NMR showed 17 mole % vinyl octyl protons, 15 mole % saturated octyl protons, and 4.3 mole % phenyl protons from the benzoyl peroxide initiator. Further characterization is presented in Table 2 and in FIG. 2, as discussed below.

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: An autoclave reactor having a volume content of 50 liters which was sufficiently substituted with nitrogen was charged in order with 20 liters of n-hexane, 12.5 mmol of triethylaluminum and 82 mmol of 1,9-decadiene and stirred for 5 minutes. Then, 3.3 g of the pre-activated metallocene supported catalyst prepared above was added, and a temperature of the reactor was elevated to 60° C. Propylene was fed so that a pressure of the reactor became a fixed pressure of 1 MPaG and reacted for 2 hours. After finishing the reaction time, 500 ml of methanol was added to terminate the reaction, and unreacted propylene was removed, followed by filtering the hexane slurry, whereby a powder of a propylene/1,9-decadiene copolymer was obtained. The powder thus obtained was dried at 60° C. for 8 hours to obtain 7 kg of the propylene/1,9-decadiene copolymer. Results of analysis thereof showed that a content of 1,9-decadiene in the copolymer was 0.03% by weight. The resulting propylene/1,9-decadiene copolymer had an MFR of 2.8 g/10 minutes. The same copolymer was produced three times to obtain total 21 kg of the propylene/1,9-decadiene copolymer, and a blend thereof was used to produce the following foamed matters. An autoclave reactor having above was added was elevated to 60° C reacted for 2 hours was added to terminate the reaction, and unreacted propylene was removed by filtering the hexane slurry, whereby a powder of a propylene/1,9-decadiene copolymer was obtained The powder thus obtained was dried at 60° C. for 8 hours

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: A mixture of cyclooctene and ethylene was contacted with catalyst and adjuvant as in Examples IX and X at room temperature and 25 psi pressure to yield 13 weight percent 1,9-decadiene. This shows that ethylene and a cyclic olefin are converted to an acyclic polyene. was contacted with catalyst and adjuvant as in Examples IX and X at room temperature