No renderable structure data available
CS(=O)C1=CC=C(C=C1)BrChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | 1-bromo-4-methylsulfinylbenzene |
|---|---|
| IUPAC Name | — |
| CAS Number | 145166-15-0 |
| Database ID | 3013958 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
1-bromo-4-methylsulfinylbenzene (CAS 145166-15-0) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 3013958
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
10 reactions · 10 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-d4839d32445e4e19a8fef575c777855fConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 4.06 g (20 mmol) of 4-bromothioanisole and 75 ml of dichloromethane were introduced into a round-bottomed flask and 6.3 g (20 mmol) of meta-chloroperbenzoic acid were added. Stirring was carried out at room temperature for four hours and the reaction mixture was poured into water. The organic phase was separated by settling, dried over magnesium sulfate and evaporated. The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30). After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide, with a melting point of 80°-81° C., was recovered. The organic phase was separated dried over magnesium sulfate evaporated The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30) After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide with a melting point of 80°-81° C., was recovered
Source ID: ord-6fba4f6b6efb461e92bb0e1d5cb1e036Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Following the basic procedure of Example 32, by reacting 1.21 g (5 mmol) of αethynyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenemethanol with 1.1 g (5 mmol) of 4-bromophenylsulfinylmethane, 177 mg (9%) of the expected sulfoxide compound, with a melting point of 121°-122° C., were obtained. with a melting point of 121°-122° C., were obtained
Source ID: ord-9257940612104583b854d0a90989b4b0Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 4.06 g (20 mmol) of 4-bromothioanisole and 75 ml of dichloromethane were introduced into a round-bottomed flask and 6.3 g (20 mmol) of meta-chloroperbenzoic acid were added. Stirring was carried out at room temperature for four hours and the reaction mixture was poured into water. The organic phase was separated by settling, dried over magnesium sulfate and evaporated. The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30). After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide, with a melting point of 80°-81° C., was recovered. The organic phase was separated dried over magnesium sulfate evaporated The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30) After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide with a melting point of 80°-81° C., was recovered
Source ID: ord-9b59cbe9856d4a9194a151eb7fe66007Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 4.06 g (20 mmol) of 4-bromothioanisole and 75 ml of dichloromethane were introduced into a round-bottomed flask and 6.3 g (20 mmol) of meta-chloroperbenzoic acid were added. Stirring was carried out at room temperature for four hours and the reaction mixture was poured into water. The organic phase was separated by settling, dried over magnesium sulfate and evaporated. The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30). After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide, with a melting point of 80°-81° C., was recovered. The organic phase was separated dried over magnesium sulfate evaporated The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30) After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide with a melting point of 80°-81° C., was recovered
Source ID: ord-9b59cbe9856d4a9194a151eb7fe66007Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-d4839d32445e4e19a8fef575c777855fConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Following the basic procedure of Example 32, by reacting 1.21 g (5 mmol) of α-ethynyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenemethanol with 1.1 g (5 mmol) of 4-bromophenylsulfinylmethane, 177 mg (9%) of the expected sulfoxide compound, with a melting point of 121°-122° C., were obtained. with a melting point of 121°-122° C., were obtained
Source ID: ord-5a7354c209534c45be0c2e8b8afe0a3cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 4.06 g (20 mmol) of 4-bromothioanisole and 75 ml of dichloromethane were introduced into a round-bottomed flask and 6.3 g (20 mmol) of meta-chloroperbenzoic acid were added. Stirring was carried out at room temperature for four hours and the reaction mixture was poured into water. The organic phase was separated by settling, dried over magnesium sulfate and evaporated. The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30). After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide, with a melting point of 80°-81° C., was recovered. The organic phase was separated dried over magnesium sulfate evaporated The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30) After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide with a melting point of 80°-81° C., was recovered
Source ID: ord-6fba4f6b6efb461e92bb0e1d5cb1e036Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Following the basic procedure of Example 32, by reacting 1.21 g (5 mmol) of αethynyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenemethanol with 1.1 g (5 mmol) of 4-bromophenylsulfinylmethane, 177 mg (9%) of the expected sulfoxide compound, with a melting point of 121°-122° C., were obtained. with a melting point of 121°-122° C., were obtained
Source ID: ord-9257940612104583b854d0a90989b4b0Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 4.06 g (20 mmol) of 4-bromothioanisole and 75 ml of dichloromethane were introduced into a round-bottomed flask and 6.3 g (20 mmol) of meta-chloroperbenzoic acid were added. Stirring was carried out at room temperature for four hours and the reaction mixture was poured into water. The organic phase was separated by settling, dried over magnesium sulfate and evaporated. The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30). After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide, with a melting point of 80°-81° C., was recovered. The organic phase was separated dried over magnesium sulfate evaporated The residue obtained was purified by chromatography on a silica column eluted with a mixture of dichloromethane and heptane (70/30) After evaporating the solvents, 1.22 g (28%) of the expected sulfoxide with a melting point of 80°-81° C., was recovered
Source ID: ord-9b59cbe9856d4a9194a151eb7fe66007PubChem References
These sources are listed in the compound's public database record.
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