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CC(C)(C)SC1=CC(=CC=C1)BrChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | 1-bromo-3-tert-butylsulfanylbenzene |
|---|---|
| IUPAC Name | — |
| CAS Number | 135883-40-8 |
| Database ID | 21400459 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
1-bromo-3-tert-butylsulfanylbenzene (CAS 135883-40-8) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 21400459
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-1784fe48a6d04a2ca304a9b6bf70e41aConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at-5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MGSO4) The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3) & 1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). 4-Bromophenyl 3-methyl-2-butenyl sulfide (Compound 46) Isobutylene was bubbled through 75% H2SO4 solution at-5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MGSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-7f4ec22995ae4d7fa214477d38dda4d4Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at-5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MGSO4) The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3) & 1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). 4-Bromophenyl 3-methyl-2-butenyl sulfide (Compound 46) Isobutylene was bubbled through 75% H2SO4 solution at-5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MGSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-7f4ec22995ae4d7fa214477d38dda4d4Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6mm) to give the title compound as a pale yellow oil. PMR (CDCl3) : & 1.30 (9H, s), 7.23 (1H, t, J-8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J-1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6mm)
Source ID: ord-929518a545964e6ab79542a587529211Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at-5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MGSO4) The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3) & 1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). 4-Bromophenyl 3-methyl-2-butenyl sulfide (Compound 46) Isobutylene was bubbled through 75% H2SO4 solution at-5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MGSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-7f4ec22995ae4d7fa214477d38dda4d4Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3): & 1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-328eb3772c304cf0ba39ab72351a0a82Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-1784fe48a6d04a2ca304a9b6bf70e41aConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3): & 1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-328eb3772c304cf0ba39ab72351a0a82Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3): δ1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-dd9306db9e724df49db3c16abbb46231Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3): δ1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-dd9306db9e724df49db3c16abbb46231Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3): δ1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-dd9306db9e724df49db3c16abbb46231Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C. until 2.65 g (47.2 mmol) of isobutylene had been absorbed. The mixture was treated with 3.8 g (20.1 mmol) of 3-bromothiophenol and then allowed to warm to room temperature and stirred for 72 hours. The reaction mixture was then poured into 40 ml of an ice/water mixture and then extracted with ether. The ether extracts were combined and washed successively with 5% NaOH, water and saturated NaCl solution and then dried (MgSO4). The solvent was removed in-vacuo and the residue distilled (69-75 degrees C., 0.6 mm) to give the title compound as a pale yellow oil. PMR (CDCl3) : & 1.30 (9H, s), 7.23 (1H, t, J~8.0 Hz), 7.45-7.54 (2H, m), 7.72 (1H, t, J~1.8 Hz). Isobutylene was bubbled through 75% H2SO4 solution at -5 degrees C extracted with ether washed successively with 5% NaOH, water and saturated NaCl solution dried (MgSO4) The solvent was removed in-vacuo the residue distilled (69-75 degrees C., 0.6 mm)
Source ID: ord-c5c9a7be22dc4f97a5a04da9c32c8e07PubChem References
These sources are listed in the compound's public database record.
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