No renderable structure data available
C1=CC=C(C=C1)OC(=O)OC2=CC=CC=C2Chemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | diphenyl carbonate |
|---|---|
| IUPAC Name | — |
| CAS Number | 102-09-0 |
| Database ID | 7597 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
diphenyl carbonate (CAS 102-09-0) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 7597
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-481edc0611df4227821beeefeab1197cConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-80e3954c6ef64e16abf59a2d79b9fb80Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-5b1529c195ea431e87027b4a16c8bdfaConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-376da4f373394e21bcf0df35266ea3cdConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-e2b662271e2549a085c2245ab6df8a2aConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-ecc9018dae5b47288db4c7f7bea97056Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-fc03f37b58044dacbad2886876a0ec66Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-e1f2c8b7703a4a6d9d6c8037e77ca24bConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-ced457d17791412392dc65f5ff963d38Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-4188da96f7cf4792a31b61e9b4142d87Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Under a nitrogen atmosphere, 428 mg (2 mmol) of diphenyl carbonate and 5 mL of acetonitrile were loaded into a round bottom flask having a volume of 100 mL, and then the mixture was stirred at room temperature. A solution prepared by dissolving 633 mg (mL) of butyltetrahydrothiophenium methionine salt in 15 mL of acetonitrile was dropped to the solution, and then the mixture was stirred for 20 minutes. After that, a 1M aqueous HCl solution was added to the reaction solution to terminate the reaction, and then the resultant was concentrated with an evaporator. Next, water was added to the concentrated product, and then the resultant was extracted with ethyl acetate. The resultant organic layer was washed with water and brine, and was then dried with sodium sulfate. After that, the dried product was concentrated with an evaporator. Thus, a crude product was obtained. Next, the crude product was purified by column chromatography. Thus, N-phenoxycarbonyl-L-methionine was obtained. An isolation amount and an isolation yield were 428.8 mg and 80%, respectively. A solution prepared was dropped to the solution the mixture was stirred for 20 minutes to terminate the reaction the resultant was concentrated with an evaporator Next, water was added to the concentrated product the resultant was extracted with ethyl acetate The resultant organic layer was washed with water and brine was then dried with sodium sulfate After that, the dried product was concentrated with an evaporator Thus, a crude product was obtained Next, the crude product was purified by column chromatography
Source ID: ord-85c6e474628f41f49b628431507ab7baConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Under a nitrogen atmosphere, 428 mg (2 mmol) of diphenyl carbonate and 5 mL of acetonitrile were loaded into a round bottom flask having a volume of 100 mL, and then the mixture was stirred at room temperature. A solution prepared by dissolving 935 mg (2 mmol) of butyltriphenylphosphonium methionine salt in 15 mL of acetonitrile was dropped to the solution, and then the mixture was stirred for 50 minutes. After that, a 1M aqueous HCl solution was added to the reaction solution to terminate the reaction, and then the resultant was concentrated with an evaporator. Next, water was added to the concentrated product, and then the resultant was extracted with ethyl acetate. The resultant organic layer was washed with water and brine, and was then dried with sodium sulfate. After that, the dried product was concentrated with an evaporator. Thus, a crude product was obtained. Next, the crude product was purified by column chromatography. Thus, N-phenoxycarbonyl-L-methionine was obtained. An isolation amount and an isolation yield were 441.5 mg and 82%, respectively. A solution prepared was dropped to the solution the mixture was stirred for 50 minutes to terminate the reaction the resultant was concentrated with an evaporator Next, water was added to the concentrated product the resultant was extracted with ethyl acetate The resultant organic layer was washed with water and brine was then dried with sodium sulfate After that, the dried product was concentrated with an evaporator Thus, a crude product was obtained Next, the crude product was purified by column chromatography
Source ID: ord-2a18fee551ab423cab5b0242fb00011ePubChem References
These sources are listed in the compound's public database record.
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