azanium;octadecanoate

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 50 g. of Gelvatol 1-90 polyvinylalcohol, 40 g. of Acrysol WS-32 acrylic polymer and 1375 ml. of water was heated to dissolve the solids until a clear solution was obtained. 250 g. of stearic acid was added which melted and dispersed in the stirred solution followed by 115 ml. of ammonium hydroxide (28% solution) which was added dropwise to the stirred dispersion of stearic acid in polymer solution. A gel of ammonium stearate was formed. 100 g. of calcium chloride dissolved in 100 ml. of water was then added to the vigorously stirred gel to precipitate the calcium soap. 350 ml. of water, 200 g. of Casco PR 247 (Borden Chemical trademark-- a cationic ureaformaldehyde wet strength resin), and 250 g. Bondfast adhesive (polyvinylacetate emulsion with 35% solids) were added and blending continued until a smooth consistency was obtained. The product was a thixotropic smooth creamy white suspension. The composition is as follows: to dissolve the solids until a clear solution was obtained dispersed in the stirred solution

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume. was then added dropwise to the gently stirred liquid An intractable gel is formed which formed After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power the preferred method of preparation because it to be obtained

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume. dissolved to form a liquid layer

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 50 g. of Gelvatol 1-90 polyvinylalcohol, 40 g. of Acrysol WS-32 acrylic polymer and 1375 ml. of water was heated to dissolve the solids until a clear solution was obtained. 250 g. of stearic acid was added which melted and dispersed in the stirred solution followed by 115 ml. of ammonium hydroxide (28% solution) which was added dropwise to the stirred dispersion of stearic acid in polymer solution. A gel of ammonium stearate was formed. 100 g. of calcium chloride dissolved in 100 ml. of water was then added to the vigorously stirred gel to precipitate the calcium soap. 350 ml. of water, 200 g. of Casco PR 247 (Borden Chemical trademark-- a cationic ureaformaldehyde wet strength resin), and 250 g. Bondfast adhesive (polyvinylacetate emulsion with 35% solids) were added and blending continued until a smooth consistency was obtained. The product was a thixotropic smooth creamy white suspension. The composition is as follows: to dissolve the solids until a clear solution was obtained dispersed in the stirred solution

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume. was then added dropwise to the gently stirred liquid An intractable gel is formed which formed After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power the preferred method of preparation because it to be obtained

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume. dissolved to form a liquid layer

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: To 100 parts of water, 60 parts of stearic acid was added, and the stearic acid was completely melted by heating to 72° C. i.e. the melting point of the stearic acid, with stirring. In this state, stearic acid is present as oil droplets in water. Then, a mixture comprising 73.9 parts of 10% aqueous ammonia and 100 parts of water, was dropwise added to the above-mentioned molten stearic acid/water mixture, with stirring, to obtain an aqueous dispersion of ammonium stearate having a solid content of 20%. with stirring

Conditions: temp:60.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: An ammonium stearate solution was prepared by mixing 113.5 grams of stearic acid with 567 grams of ammonia/carbon dioxide solution containing 12% of ammonia and 10% of carbon dioxide. The solution was sprayed onto 756 grams of zinc clay R591, then the mixture was mixed well and heated to 60° C. The resulting powder was heated at 110° C. for 18 hours. The dried powder was attrition milled again and then sieved with a 140 mesh sieve. The product was jet milled with the Nissen jet mill (see Example 2) to produce zinc stearate clay RC. There is some loss of material through dusting at the various milling processes. Its properties are listed below: the mixture was mixed well The resulting powder was heated at 110° C. for 18 hours attrition milled again sieved with a 140 mesh sieve milled with the Nissen jet mill (see Example 2)

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 50 g. of Gelvatol 1-90 polyvinylalcohol, 40 g. of Acrysol WS-32 acrylic polymer and 1375 ml. of water was heated to dissolve the solids until a clear solution was obtained. 250 g. of stearic acid was added which melted and dispersed in the stirred solution followed by 115 ml. of ammonium hydroxide (28% solution) which was added dropwise to the stirred dispersion of stearic acid in polymer solution. A gel of ammonium stearate was formed. 100 g. of calcium chloride dissolved in 100 ml. of water was then added to the vigorously stirred gel to precipitate the calcium soap. 350 ml. of water, 200 g. of Casco PR 247 (Borden Chemical trademark-- a cationic ureaformaldehyde wet strength resin), and 250 g. Bondfast adhesive (polyvinylacetate emulsion with 35% solids) were added and blending continued until a smooth consistency was obtained. The product was a thixotropic smooth creamy white suspension. The composition is as follows: to dissolve the solids until a clear solution was obtained dispersed in the stirred solution

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume. was then added dropwise to the gently stirred liquid An intractable gel is formed which formed After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power the preferred method of preparation because it to be obtained

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 272 ml. of water, 10 g. of Gelvatol 1-90 polyvinylalcohol and 5 g. of Acrysol WS-32 acrylic polymer were heated until the binders dissolved. 50 g. of stearic acid was then added and melted to form a liquid layer floating on the aqueous solution. 23 ml. of ammonium hyroxide (28% solution), which was the stoichiometric amount to form ammonium stearate, was then added dropwise to the gently stirred liquid. An intractable gel is formed which was transferred to a vigorously-stirred Waring Blendor, and then 20 g. of calcium chloride dissolved in 20 ml. of water slowly added until the mixture became solid. 50 ml. of water was then added with stirring until a creamy paste formed. After drying on a substrate this material gave a pressure-sensitive film with excellent hiding power. The formation of ammonium stearate in situ is the preferred method of preparation because it allows a higher solids content to be obtained and yields smaller particles of calcium stearate. The density of the dry coating was 0.5 g./cc which is equivalent to about 50% void volume. dissolved to form a liquid layer