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CCP(CC)ClChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | chloro(diethyl)phosphane |
|---|---|
| IUPAC Name | — |
| CAS Number | 686-69-1 |
| Database ID | 69639 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
chloro(diethyl)phosphane (CAS 686-69-1) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 69639
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-36a90885e9214c02ae2dfc6a57d850dcConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-methoxyphenyllithium [prepared from 23.4 g. (0.1 mole) of p-iodoanisole in 100 ml. of ether and 62.5 ml. of 1.6 M n-butyllithium in hexane] under a nitrogen atmosphere. After 40 minutes, the reaction mixture was filtered and the solvent removed at reduced pressure. Distillation of the residual oil gave (diethyl) (p-methoxyphenyl)phosphine as a colorless liquid, b.p. 85°-90° C. at 0.5 mm. the reaction mixture was filtered the solvent removed at reduced pressure Distillation of the residual oil
Source ID: ord-3a34afcc336541b8b624a0c24a00e46cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-chlorophenyllithium [prepared from 15.4 g. (0.08 mole) of p-chlorobromobenzene in 100 ml. of ether and 54 ml. of 1.5M n-butyllithium in hexane] under a nitrogen atmosphere. After 30 minutes, the reaction mixture was quenched with a few drops of ethyl acetate and the solvent was removed at reduced pressure. Distillation of the residual oil gave (p-chlorophenyl) (diethyl)phosphine, b.p. 86°-89° C. at 1.5 mm. the reaction mixture was quenched with a few drops of ethyl acetate the solvent was removed at reduced pressure Distillation of the residual oil
Source ID: ord-58928434ae5c48f7a799bc0a8e1d4493Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-methoxyphenyllithium [prepared from 23.4 g. (0.1 mole) of p-iodoanisole in 100 ml. of ether and 62.5 ml. of 1.6 M n-butyllithium in hexane] under a nitrogen atmosphere. After 40 minutes, the reaction mixture was filtered and the solvent removed at reduced pressure. Distillation of the residual oil gave (diethyl)(p-methoxyphenyl)phosphine as a colorless liquid, b.p. 85°-90° C. at 0.5 mm. the reaction mixture was filtered the solvent removed at reduced pressure Distillation of the residual oil
Source ID: ord-3f82d9807b7849d1a9c41cf9b6979506Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-methoxyphenyllithium [prepared from 23.4 g. (0.1 mole) of p-iodoanisole in 100 ml. of ether and 62.5 ml. of 1.6 M n-butyllithium in hexane] under a nitrogen atmosphere. After 40 minutes, the reaction mixture was filtered and the solvent removed at reduced pressure. Distillation of the residual oil gave (diethyl)(p-methoxyphenyl)phosphine as a colorless liquid, b.p. 85°-90° C. at 0.5 mm. the reaction mixture was filtered the solvent removed at reduced pressure Distillation of the residual oil
Source ID: ord-3f82d9807b7849d1a9c41cf9b6979506Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-chlorophenyllithium [prepared from 15.4 g. (0.08 mole) of p-chlorobromobenzene in 100 ml. of ether and 54 ml. of 1.5M n-butyllithium in hexane] under a nitrogen atmosphere. After 30 minutes, the reaction mixture was quenched with a few drops of ethyl acetate and the solvent was removed at reduced pressure. Distillation of the residual oil gave (p-chlorophenyl)(diethyl)phosphine, b.p. 86°-89° C. at 1.5 mm. the reaction mixture was quenched with a few drops of ethyl acetate the solvent was removed at reduced pressure Distillation of the residual oil
Source ID: ord-3a32cbd09da144fd96f6f8bbc60fdf6dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-methoxyphenyllithium [prepared from 23.4 g. (0.1 mole) of p-iodoanisole in 100 ml. of ether and 62.5 ml. of 1.6 M n-butyllithium in hexane] under a nitrogen atmosphere. After 40 minutes, the reaction mixture was filtered and the solvent removed at reduced pressure. Distillation of the residual oil gave (diethyl) (p-methoxyphenyl)phosphine as a colorless liquid, b.p. 85°-90° C. at 0.5 mm. the reaction mixture was filtered the solvent removed at reduced pressure Distillation of the residual oil
Source ID: ord-3a34afcc336541b8b624a0c24a00e46cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-chlorophenyllithium [prepared from 15.4 g. (0.08 mole) of p-chlorobromobenzene in 100 ml. of ether and 54 ml. of 1.5M n-butyllithium in hexane] under a nitrogen atmosphere. After 30 minutes, the reaction mixture was quenched with a few drops of ethyl acetate and the solvent was removed at reduced pressure. Distillation of the residual oil gave (p-chlorophenyl) (diethyl)phosphine, b.p. 86°-89° C. at 1.5 mm. the reaction mixture was quenched with a few drops of ethyl acetate the solvent was removed at reduced pressure Distillation of the residual oil
Source ID: ord-58928434ae5c48f7a799bc0a8e1d4493Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-chlorophenyllithium [prepared from 15.4 g. (0.08 mole) of p-chlorobromobenzene in 100 ml. of ether and 54 ml. of 1.5M n-butyllithium in hexane] under a nitrogen atmosphere. After 30 minutes, the reaction mixture was quenched with a few drops of ethyl acetate and the solvent was removed at reduced pressure. Distillation of the residual oil gave (p-chlorophenyl) (diethyl)phosphine, b.p. 86°-89° C. at 1.5 mm. the reaction mixture was quenched with a few drops of ethyl acetate the solvent was removed at reduced pressure Distillation of the residual oil
Source ID: ord-58928434ae5c48f7a799bc0a8e1d4493Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-36a90885e9214c02ae2dfc6a57d850dcConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-methoxyphenyllithium [prepared from 23.4 g. (0.1 mole) of p-iodoanisole in 100 ml. of ether and 62.5 ml. of 1.6 M n-butyllithium in hexane] under a nitrogen atmosphere. After 40 minutes, the reaction mixture was filtered and the solvent removed at reduced pressure. Distillation of the residual oil gave (diethyl)(p-methoxyphenyl)phosphine as a colorless liquid, b.p. 85°-90° C. at 0.5 mm. the reaction mixture was filtered the solvent removed at reduced pressure Distillation of the residual oil
Source ID: ord-3f82d9807b7849d1a9c41cf9b6979506Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A solution of 10 g. (0.08 mole) of diethylphosphinous chloride in 100 ml. of ether was added to a solution of p-chlorophenyllithium [prepared from 15.4 g. (0.08 mole) of p-chlorobromobenzene in 100 ml. of ether and 54 ml. of 1.5M n-butyllithium in hexane] under a nitrogen atmosphere. After 30 minutes, the reaction mixture was quenched with a few drops of ethyl acetate and the solvent was removed at reduced pressure. Distillation of the residual oil gave (p-chlorophenyl)(diethyl)phosphine, b.p. 86°-89° C. at 1.5 mm. the reaction mixture was quenched with a few drops of ethyl acetate the solvent was removed at reduced pressure Distillation of the residual oil
Source ID: ord-3a32cbd09da144fd96f6f8bbc60fdf6dPubChem References
These sources are listed in the compound's public database record.
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