tridecan-1-amine

Conditions: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 19.8 g of malononitrile were dissolved in 30 ml of DMF and cooled to 0° C. While cooling, 61 g of triethylamine and 27 g of chloroacetyl chloride were simultaneously added dropwise to this, and the mixture was stirred at 10° C. for 10 minutes. 65.7 g of tridecylamine were then added dropwise, and the reaction mixture was stirred at room temperature for 48 hours. 300 ml of isopropylamine were then added to the mixture, which was refluxed for 2 hours, 10 g of active carbon were added, and the mixture was filtered hot. After cooling, the precipitate was filtered off with suction, washed and dried at 50° C. 40 g (44% of theory) of the compound of the formula ##STR25## of melting point 214° to 215° C. were obtained. The IR, NMR, UV and mass spectra and the elemental analysis are consistent with the structural formula. While cooling the reaction mixture was stirred at room temperature for 48 hours was refluxed for 2 hours 10 g of active carbon were added the mixture was filtered hot After cooling the precipitate was filtered off with suction washed dried at 50° C 40 g (44% of theory) of the compound of the formula ##STR25## of melting point 214° to 215° C. were obtained

Conditions: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 19.8 g of malononitrile were dissolved in 30 ml of DMF and cooled to 0° C. While cooling, 61 g of triethylamine and 27 g of chloroacetyl chloride were simultaneously added dropwise to this, and the mixture was stirred at 10° C. for 10 minutes. 65.7 g of tridecylamine were then added dropwise, and the reaction mixture was stirred at room temperature for 48 hours. 300 ml of isopropylamine were then added to the mixture, which was refluxed for 2 hours, 10 g of active carbon were added, and the mixture was filtered hot. After cooling, the precipitate was filtered off with suction, washed and dried at 50° C. 40 g (44% of theory) of the compound of the formula ##STR25## of melting point 214° to 215° C. were obtained. The IR, NMR, UV and mass spectra and the elemental analysis are consistent with the structural formula. While cooling the reaction mixture was stirred at room temperature for 48 hours was refluxed for 2 hours 10 g of active carbon were added the mixture was filtered hot After cooling the precipitate was filtered off with suction washed dried at 50° C 40 g (44% of theory) of the compound of the formula ##STR25## of melting point 214° to 215° C. were obtained

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 288 parts of β-naphthol, 9 parts of triphenyl phosphite and 418 parts of tridecylamine are heated to 175° C, whilst stirring. The elimination of water commences at this temperature and has ended after 10 hours, when the internal temperature is 230° C and 36 parts of water have been removed. Excess β-naphthol and amine are distilled off in vacuo. 2-Tridecyl-naphthylamine is then distilled at a boiling point of 225° C/3 mm Hg. 630 parts of end product are obtained, corresponding to a yield of 97% of theory. is 230° C 36 parts of water have been removed Excess β-naphthol and amine are distilled off in vacuo 2-Tridecyl-naphthylamine is then distilled at a boiling point of 225° C/3 mm Hg 630 parts of end product are obtained, corresponding to a yield of 97% of theory

Conditions: temp:0.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 19.8 g of malononitrile were dissolved in 30 ml of DMF and cooled to 0° C. While cooling, 61 g of triethylamine and 27 g of chloroacetyl chloride were simultaneously added dropwise to this, and the mixture was stirred at 10° C. for 10 minutes. 65.7 g of tridecylamine were then added dropwise, and the reaction mixture was stirred at room temperature for 48 hours. 300 ml of isopropylamine were then added to the mixture, which was refluxed for 2 hours, 10 g of active carbon were added, and the mixture was filtered hot. After cooling, the precipitate was filtered off with suction, washed and dried at 50° C. 40 g (44% of theory) of the compound of the formula ##STR25## of melting point 214° to 215° C. were obtained. The IR, NMR, UV and mass spectra and the elemental analysis are consistent with the structural formula. While cooling the reaction mixture was stirred at room temperature for 48 hours was refluxed for 2 hours 10 g of active carbon were added the mixture was filtered hot After cooling the precipitate was filtered off with suction washed dried at 50° C 40 g (44% of theory) of the compound of the formula ##STR25## of melting point 214° to 215° C. were obtained