No renderable structure data available
CC(C)CCCCCCCCCCCCCOChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | 14-methylpentadecan-1-ol |
|---|---|
| IUPAC Name | — |
| CAS Number | 20194-48-3 |
| Database ID | 5283265 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
14-methylpentadecan-1-ol (CAS 20194-48-3) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 5283265
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
10 reactions · 10 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-388f3edb183f437e98f6c2a677bc71c7Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-62bdb33e76ca4f0aa708b8e4116048f0Conditions: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Iso-hexadecyl nicotinate was prepared from nicotinic acid and a commercial material, iso-hexadecyl alcohol, obtained from Farbwerke Hoechst AG. The general method of Example 1 was used except that the temperature after thionyl chloride addition was maintained at 80° C. for 2 hours, and after the esterification reaction the solution was cooled and washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water. The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour, filtered and the solvent removed under reduced pressure. The light brown oil had an estimated purity of 93.4% and was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8% estimated purity. after the esterification reaction the solution was cooled washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour filtered the solvent removed under reduced pressure was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8%
Source ID: ord-e243b8aeb11e40868c3fc8c41e7e5e12Conditions: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Iso-hexadecyl nicotinate was prepared from nicotinic acid and a commercial material, iso-hexadecyl alcohol, obtained from Farbwerke Hoechst AG. The general method of Example 1 was used except that the temperature after thionyl chloride addition was maintained at 80° C. for 2 hours, and after the esterification reaction the solution was cooled and washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water. The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour, filtered and the solvent removed under reduced pressure. The light brown oil had an estimated purity of 93.4% and was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8% estimated purity. after the esterification reaction the solution was cooled washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour filtered the solvent removed under reduced pressure was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8%
Source ID: ord-e243b8aeb11e40868c3fc8c41e7e5e12Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-388f3edb183f437e98f6c2a677bc71c7Conditions: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Iso-hexadecyl nicotinate was prepared from nicotinic acid and a commercial material, iso-hexadecyl alcohol, obtained from Farbwerke Hoechst AG. The general method of Example 1 was used except that the temperature after thionyl chloride addition was maintained at 80° C. for 2 hours, and after the esterification reaction the solution was cooled and washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water. The solution was treated with activated carbon (2.5 % on the expected weight of product) at 50° C. for 1 hour, filtered and the solvent removed under reduced pressure. The light brown oil had an estimated purity of 93.4% and was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8% estimated purity. after the esterification reaction the solution was cooled washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water The solution was treated with activated carbon (2.5 % on the expected weight of product) at 50° C. for 1 hour filtered the solvent removed under reduced pressure was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8%
Source ID: ord-c9a7f9644daf41f1a09845e4923845f7Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 14-methylpentadecan-1-ol was prepared from 9-bromononanol and 5-methylhexylbromide in 55% yield. The 1H NMR and MS-ESI data matched those reported by Yuasa et al. (Yuasa and Tsuruta (2004) Flavour and Fragrance Journal 19:199-204).
Source ID: ord-85af44fe06d44b07baca65b45c22147fConditions: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Iso-hexadecyl nicotinate was prepared from nicotinic acid and a commercial material, iso-hexadecyl alcohol, obtained from Farbwerke Hoechst AG. The general method of Example 1 was used except that the temperature after thionyl chloride addition was maintained at 80° C. for 2 hours, and after the esterification reaction the solution was cooled and washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water. The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour, filtered and the solvent removed under reduced pressure. The light brown oil had an estimated purity of 93.4% and was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8% estimated purity. after the esterification reaction the solution was cooled washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour filtered the solvent removed under reduced pressure was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8%
Source ID: ord-86d72f3bdef140eab872014c8d7dc739Conditions: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Iso-hexadecyl nicotinate was prepared from nicotinic acid and a commercial material, iso-hexadecyl alcohol, obtained from Farbwerke Hoechst AG. The general method of Example 1 was used except that the temperature after thionyl chloride addition was maintained at 80° C. for 2 hours, and after the esterification reaction the solution was cooled and washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water. The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour, filtered and the solvent removed under reduced pressure. The light brown oil had an estimated purity of 93.4% and was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8% estimated purity. after the esterification reaction the solution was cooled washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour filtered the solvent removed under reduced pressure was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8%
Source ID: ord-50578ebbd2ac4b8ea2268360a8aedd98Conditions: temp:80.01; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Iso-hexadecyl nicotinate was prepared from nicotinic acid and a commercial material, iso-hexadecyl alcohol, obtained from Farbwerke Hoechst AG. The general method of Example 1 was used except that the temperature after thionyl chloride addition was maintained at 80° C. for 2 hours, and after the esterification reaction the solution was cooled and washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water. The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour, filtered and the solvent removed under reduced pressure. The light brown oil had an estimated purity of 93.4% and was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8% estimated purity. after the esterification reaction the solution was cooled washed with 0.5M sodium hydroxide, 0.5M hydrochloric acid and water The solution was treated with activated carbon (2.5% on the expected weight of product) at 50° C. for 1 hour filtered the solvent removed under reduced pressure was distilled (boiling range 141°-146° C. at 0.03 mm mercury pressure) to provide a product of 99.8%
Source ID: ord-e243b8aeb11e40868c3fc8c41e7e5e12PubChem References
These sources are listed in the compound's public database record.
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