decan-3-ol

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 3-decanol and 4-decanol (1.10 mmol); 2-decanone (1.73 mmol); 3-decanone and 4-decanone (1.41 mmol).

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 3-decanol and 4-decanol (1.10 mmol); 2-decanone (1.73 mmol); 3-decanone and 4-decanone (1.41 mmol).

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: In the same reactor as used in Example 1, 760 kg (5 kmoles) of tricyclo[5.2.1.02,6 ]deca-8-yl alcohol and 1500 kg (15 kmoles) of methyl methacrylate were placed and well mixed with stirring. The water content of the mixture was 2500 ppm. To the mixture, 550 g of hydroquinone monomethyl ether and 3 kg of anhydrous lithium hydroxide were added to carry out the reaction. While refluxing methyl methacrylate through the distillation column, by-produced methanol was removed by distillation. The reaction was continued until almost no methanol was produced (about 7 hours). After removing unreacted methyl methacrylate by distillation under reduced pressure, the reaction mixture was cooled and filtered under pressure (2 kg/cm2) using a filter paper (pore size 0.1 mm, area 5 m2) placing thereon 10 kg of diatomaceous earth to yield 975 kg of tricyclo[5.2.1.02,6 ]deca-8-yl methacrylate with the filtrating time of 5.5 hours. well mixed the reaction through the distillation column by-produced methanol was removed by distillation was produced (about 7 hours) After removing unreacted methyl methacrylate by distillation under reduced pressure the reaction mixture was cooled filtered under pressure (2 kg/cm2)

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: In the same reactor as used in Example 1, 760 kg (5 kmoles) of tricyclo[5.2.1.02,6 ]deca-8-yl alcohol and 1500 kg (15 kmole) of methyl methacrylate were placed and well mixed with stirring. The water content of the resulting mixture was 2500 ppm. To the mixture, 550 g of hydroquinone monomethyl ether was added and heated while introducing thereinto dried air at a rate of 4 m3/ hr and reluxing methyl methacrylate through the distillation column to remove water by azeotropic distillation. After 1 hour from the beginning of the reflux of methyl methacrylate, the water content in the reactor became 630 ppm. Then, 3 kg of anhydrous lithium hydroxide was charged into the reactor to carry out the reaction. While removing methanol by-produced by the reaction from the reaction system by distillation, the reaction was continued until almost no methanol was distilled (about 7 hours), followed by removal of unreacted methyl methacrylate under reduced pressure. After cooling, the mixture was filtered under pressure (2 kg/cm2) using a filter paper (pore size 0.1 mm, area 5 m2) placing thereon 10 kg of diatomaceous earth to yield 990 kg of tricyclo[5.2.1.02,6 ]deca-8-yl methacrylate with the filtrating time of 2 hours. well mixed heated while introducing thereinto dried air at a rate of 4 m3/ hr and reluxing methyl methacrylate through the distillation column to remove water by azeotropic distillation After 1 hour from the beginning of the reflux of methyl methacrylate Then, 3 kg of anhydrous lithium hydroxide was charged into the reactor the reaction While removing methanol by-produced by the reaction from the reaction system by distillation was distilled (about 7 hours) followed by removal of unreacted methyl methacrylate under reduced pressure After cooling the mixture was filtered under pressure (2 kg/cm2)

Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

Procedure: 3-decanol and 4-decanol (1.10 mmol); 2-decanone (1.73 mmol); 3-decanone and 4-decanone (1.41 mmol).