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CCOP(=S)(Cl)ClChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | dichloro-ethoxy-sulfanylidene-lambda5-phosphane |
|---|---|
| IUPAC Name | — |
| CAS Number | 1498-64-2 |
| Database ID | 73907 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
dichloro-ethoxy-sulfanylidene-lambda5-phosphane (CAS 1498-64-2) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 73907
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
11 reactions · 11 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-56e3330ec52e4c5cbfae932f7ce56f6dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% NaH (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-66a26007bead46f39f626b296ed20fc2Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-56e3330ec52e4c5cbfae932f7ce56f6dConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% Nail (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4 M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-36cb6b5876584a5a96730f062662d7beConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% Nail (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4 M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-36cb6b5876584a5a96730f062662d7beConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% Nail (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4 M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-36cb6b5876584a5a96730f062662d7beConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% NaH (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4 m 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45-50° C. 1 torr)
Source ID: ord-deff895b5cbf47998e8bbee8d1ac0ed1Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% NaH (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 214, 4.4 M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-5e3b00dea4ee4fb7bed7a5f7f30b86dcConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% NaH (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50 20 C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50 20 C. 1 torr)
Source ID: ord-0a56f19b36e34a869ed5c6185156d8e7Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% NaH (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-ed45dc17f2de4ca7a18e85bc18e09f7cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: To 30 g (167 mmole) of O-ethyl dichlorothiophosphate in 100 ml of tetrahydrofuran (THF) and cooled to -70° C. was added a solution of sodium propoxide (from 7.4 g of 60% NaH (184 mmole) and 11 g (176 mmole) of 1-propanol) in 50 ml of THF. After warming to room temperature over 2 hours, the THF was removed in vacuo and the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water. The organic layer was dried over magnesium sulfate, concentrated in vacuo, and distilled (bp 45°-50° C. 1 torr) yielding 20 g of the title compound, an oil. nmr 1.0 t 3H, 1.4 t 3H, 1.8 sextet 2H, 4.4M 4H. the THF was removed in vacuo the residue was partitioned between 50 ml diethyl ether, 50 ml hexanes, and 25 ml cold water The organic layer was dried over magnesium sulfate concentrated in vacuo distilled (bp 45°-50° C. 1 torr)
Source ID: ord-66a26007bead46f39f626b296ed20fc2PubChem References
These sources are listed in the compound's public database record.
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