No renderable structure data available
CCOC1=C(C=C(C=C1)Br)COChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | (5-bromo-2-ethoxyphenyl)methanol |
|---|---|
| IUPAC Name | — |
| CAS Number | 149489-18-9 |
| Database ID | 24721639 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
(5-bromo-2-ethoxyphenyl)methanol (CAS 149489-18-9) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 24721639
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-1609122d23ac42898a691aa0f5845a5fConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-ethoxybenzyl alcohol (2.78 g, 12.0 mmol) and pyridinium dichromate (4.51 g, 12.0 mmol) in 120 ml of CH2Cl2 was stirred at RT for 6 h. The mixture was filtered, washed with H2O, 0.5 N HCl and brine and dried over Na2SO4. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100) to give 5-bromo-2-ethoxybenzaldehyde. The mixture was filtered washed with H2O, 0.5 N HCl and brine dried over Na2SO4 The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100)
Source ID: ord-0e694943e7e64ef7ba6ea70287103c46Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-hydroxybenzylalcohol (5.0 g, 24.6 mmol), ethyl iodide (11.5 g, 73.8 mmol) and K2CO3 (3.4 g, 24.6 mmol) in 50 ml of acetone was stirred at +50° C. overnight. The mixture was filtered and evaporated. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100) to give 5-bromo-2-ethoxybenzyl alcohol. The mixture was filtered evaporated The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100)
Source ID: ord-845b6dd65fe44b50940e75e44f98c54cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-ethoxybenzyl alcohol (2.78 g, 12.0 mmol) and pyridinium dichromate (4.51 g, 12.0 mmol) in 120 ml of CH2Cl2 was stirred at RT for 6 h. The mixture was filtered, washed with H2O, 0.5N HCl and brine and dried over Na2SO4. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100) to give 5-bromo-2-ethoxybenzaldehyde. The mixture was filtered washed with H2O, 0.5N HCl and brine dried over Na2SO4 The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100)
Source ID: ord-14ed117b41fe4638a869c64991c7f68eConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-ethoxybenzyl alcohol (2.78 g, 12.0 mmol) and pyridinium dichromate (4.51 g, 12.0 mmol) in 120 ml of CH2Cl2 was stirred at RT for 6 h. The mixture was filtered, washed with H2O, 0.5N HCl and brine and dried over Na2SO4. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100) to give 5-bromo-2-ethoxybenzaldehyde. The mixture was filtered washed with H2O, 0.5N HCl and brine dried over Na2SO4 The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100)
Source ID: ord-14ed117b41fe4638a869c64991c7f68eConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-hydroxybenzylalcohol (5.0 g, 24.6 mmol), ethyl iodide (11.5 g, 73.8 mmol) and K2CO3 (3.4 g, 24.6 mmol) in 50 ml of acetone was stirred at +50° C. overnight. The mixture was filtered and evaporated. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100) to give 5-bromo-2-ethoxybenzyl alcohol. The mixture was filtered evaporated The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100)
Source ID: ord-05b0af491b934a388520302aeb1a6f32Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-ethoxybenzyl alcohol (2.78 g, 12.0 mmol) and pyridinium dichromate (4.51 g, 12.0 mmol) in 120 ml of CH2Cl2 was stirred at RT for 6 h. The mixture was filtered, washed with H2O, 0.5 N HCl and brine and dried over Na2SO4. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100) to give 5-bromo-2-ethoxybenzaldehyde. The mixture was filtered washed with H2O, 0.5 N HCl and brine dried over Na2SO4 The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100)
Source ID: ord-0e694943e7e64ef7ba6ea70287103c46Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-hydroxybenzylalcohol (5.0 g, 24.6 mmol), ethyl iodide (11.5 g, 73.8 mmol) and K2CO3 (3.4 g, 24.6 mmol) in 50 ml of acetone was stirred at +50° C. overnight. The mixture was filtered and evaporated. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100) to give 5-bromo-2-ethoxybenzyl alcohol. The mixture was filtered evaporated The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100)
Source ID: ord-845b6dd65fe44b50940e75e44f98c54cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-ethoxybenzyl alcohol (2.78 g, 12.0 mmol) and pyridinium dichromate (4.51 g, 12.0 mmol) in 120 ml of CH2Cl2 was stirred at RT for 6 h. The mixture was filtered, washed with H2O, 0.5N HCl and brine and dried over Na2SO4. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100) to give 5-bromo-2-ethoxybenzaldehyde. The mixture was filtered washed with H2O, 0.5N HCl and brine dried over Na2SO4 The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100)
Source ID: ord-3747722cd3434d0781851750915a78c8Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-hydroxybenzylalcohol (5.0 g, 24.6 mmol), ethyl iodide (11.5 g, 73.8 mmol) and K2CO3 (3.4 g, 24.6 mmol) in 50 ml of acetone was stirred at +50° C. overnight. The mixture was filtered and evaporated. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100) to give 5-bromo-2-ethoxybenzyl alcohol. The mixture was filtered evaporated The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100)
Source ID: ord-2a8ca8f5fa924a91b25320bbdcbccc90Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-ethoxybenzyl alcohol (2.78 g, 12.0 mmol) and pyridinium dichromate (4.51 g, 12.0 mmol) in 120 ml of CH2Cl2 was stirred at RT for 6 h. The mixture was filtered, washed with H2O, 0.5N HCl and brine and dried over Na2SO4. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100) to give 5-bromo-2-ethoxybenzaldehyde. The mixture was filtered washed with H2O, 0.5N HCl and brine dried over Na2SO4 The product was purified by silica gel column chromatography (EtOAc/petroleum ether 10:100)
Source ID: ord-14ed117b41fe4638a869c64991c7f68eConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: 5-Bromo-2-hydroxybenzylalcohol (5.0 g, 24.6 mmol), ethyl iodide (11.5 g, 73.8 mmol) and K2CO3 (3.4 g, 24.6 mmol) in 50 ml of acetone was stirred at +50° C. overnight. The mixture was filtered and evaporated. The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100) to give 5-bromo-2-ethoxybenzyl alcohol. The mixture was filtered evaporated The product was purified by silica gel column chromatography (EtOAc/petroleum ether 30:100)
Source ID: ord-05b0af491b934a388520302aeb1a6f32PubChem References
These sources are listed in the compound's public database record.
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