No renderable structure data available
CCCCCC[Si](C)(Cl)ClChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | dichloro-hexyl-methylsilane |
|---|---|
| IUPAC Name | — |
| CAS Number | 14799-94-1 |
| Database ID | 84650 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
dichloro-hexyl-methylsilane (CAS 14799-94-1) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 84650
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
11 reactions · 11 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-4b92ddfefd244d708e934119eefea294Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: In the same apparatus and procedure as Example 1 above, 0.15 g (0.75 mmol) of tri-n-butylphosphine, 0.90 g (7.5 mmol) of 1-chlorohexane, and 3.90 ml (37.5 mmol) of methyldichlorosilane were reacted at 150° C. for 12 hrs. The resulting mixture was distilled to give 0.25 g of 2,2-dichloro-2-silaoctane (yield:16%). The resulting mixture was distilled
Source ID: ord-a4b61707bd094a13bf1dbeeff4eb633fConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to -78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to -78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-b0f7a404bfaa4fbdb6970bf8c98aea01Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to −78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to −78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-9e51f368cd4d4572a3bee8423fe3622cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to −78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to −78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-97bdd300fb3e4454abe200c5e65643f9Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-4b92ddfefd244d708e934119eefea294Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to -78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to -78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-aa4ec8095dc94e3ca39ff02f7e86a7e2Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: In the same apparatus and procedure as Example 1 above, 0.15 g (0.75 mmol) of tri-n-butylphosphine, 0.90 g (7.5 mmol) of 1-chlorohexane, and 3.90 ml (37.5 mmol) of methyldichlorosilane were reacted at 150° C. for 12 hrs. The resulting mixture was distilled to give 0.25 g of 2,2-dichloro-2-silaoctane (yield:16%). The resulting mixture was distilled
Source ID: ord-a4b61707bd094a13bf1dbeeff4eb633fConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to -78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to -78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-b0f7a404bfaa4fbdb6970bf8c98aea01Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to −78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to −78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-9e51f368cd4d4572a3bee8423fe3622cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: n-Hexylmethyldichlorosilane (30.4 g, 0.152 mol) and 300 mL of dry THF were charged to a one liter Schlenk equipped with an addition funnel. Fluorene anion (52.4 g, 0.305 mol) was dissolved in approximately 200 mL of dry THF and charged to the addition funnel. The temperature of the stirring solution was lowered to −78° C. under positive nitrogen pressure. The fluorene anion was added dropwise over two hours. After the anion addition was complete, the reaction mixture was allowed to warm to room temperature. The solution was allowed to stir overnight. The solution was washed with three 200 mL aliquots of water, retaining the organic layer after each washing. The organic layer was dried with magnesium sulfate and filtered. The product was recrystallized from hexane. The yield of this reaction is 19.6%. equipped with an addition funnel charged to the addition funnel was lowered to −78° C. under positive nitrogen After the anion addition The solution was washed with three 200 mL aliquots of water The organic layer was dried with magnesium sulfate filtered The product was recrystallized from hexane
Source ID: ord-97bdd300fb3e4454abe200c5e65643f9PubChem References
These sources are listed in the compound's public database record.
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