No renderable structure data available
C1=CC=C(C=C1)CN=CC2=CC=CC=C2OChemical Intermediate
Structures, identifiers and computed properties have been matched to the database record by CAS.
| Intermediates | 2-(benzyliminomethyl)phenol |
|---|---|
| IUPAC Name | — |
| CAS Number | 129855-29-4 |
| Database ID | 71643 |
| Molecular Formula | — |
| Molecular Weight | — |
Product Information
2-(benzyliminomethyl)phenol (CAS 129855-29-4) product identity, structure identifiers and related reaction data for chemical intermediate research and sourcing review.
Potential Applications
For professional research and industrial use only
Database ID 71643
Safety Notice
For professional research and industrial use only. Review the supplier safety data sheet before handling.
Synthesis data
12 reactions · 12 references
Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-2ab6ba81821b42c68b60f8df89d25c66Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-e0b62d382abb43bd9e675e1bd735f479Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: This compound was prepared from 2.7 g of 2-hydroxy-5-methoxy-benzaldehyde, 2.3 mL of benzylamine and 0.03 g of p-toluenesulphonic acid using the procedure described for 64a. Yield: 4:3 g (oil).
Source ID: ord-9a275bf7cc864595a16b0d6ee571150cConditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
Source ID: ord-6c93f9cb25fe4e1da7bc99a37d5557d1Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
Source ID: ord-6c93f9cb25fe4e1da7bc99a37d5557d1Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A mixture of 5.0 mL of 2-hydroxy-benzaldehyde, 6.3 mL of benzylamine and 0.05 g of p-toluenesulphonic acid was refluxed in toluene for 2 hours using a Dean-Stark trap to remove liberated water. The volatiles were removed in vacuo yielding 10.1 g of crude 2-(benzylimino-methyl)-phenol to remove liberated water The volatiles were removed in vacuo
Source ID: ord-affc3acba4bf49088ca5ffae9dd847d4Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: This compound was prepared from 2.7 g of 2-hydroxy-5-methoxy-benzaldehyde, 2.3 mL of benzylamine and 0.03 g of p-toluenesulphonic acid using the procedure described for 64a. Yield: 4.3 g (oil).
Source ID: ord-d0b227a7913f4de890cf6d104fc511d6Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
Source ID: ord-e5c58b6a217b48718b255c5b288ea419Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: Sodium borohydride (0.2 g) was added in small portions to 3 mL of dry 2-propanol in a nitrogen atmosphere. To this mixture was added dropwise a solution of 1.0 g of 2-(benzylimino-methyl)-phenol in 3 mL of 2-propanol. After complete addition, stirring was continued for 1 h. Then water was added in order to decompose excess borohydride, and the volatiles were removed in vacuo. The residue was redissolved in ethyl acetate, washed with water, dried (sodium sulfate) and concentrated yielding 0.9 g of 2-(benzylamino-methyl)-phenol as an oil. EI-MS: 213 (M+). After complete addition the volatiles were removed in vacuo The residue was redissolved in ethyl acetate washed with water dried (sodium sulfate) concentrated
Source ID: ord-e5c58b6a217b48718b255c5b288ea419Conditions: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
Procedure: A mixture of 5.0 mL of 2-hydroxy-benzaldehyde, 6.3 mL of benzylamine and 0.05 g of p-toluenesulphonic acid was refluxed in toluene for 2 hours using a Dean-Stark trap to remove liberated water. The volatiles were removed in vacuo yielding 10.1 g of crude 2-(benzylimino-methyl)-phenol. to remove liberated water The volatiles were removed in vacuo
Source ID: ord-f2746416d45a48fb96a40d3ce0b856cdConditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-2ab6ba81821b42c68b60f8df89d25c66Conditions: temp:0.00; pressure:0.00; stir:
Source ID: ord-e0b62d382abb43bd9e675e1bd735f479PubChem References
These sources are listed in the compound's public database record.
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